Whole-rock chemistry of the Gameleira I uranium deposit,Lagoa Real,Brazil     

《Chemie der Erde / Geochemistry》2021,81(1):125677

The Lagoa Real uranium (U) province, referred to as Lagoa Real, is located in the state of Bahia, north-eastern Brazil. Lagoa Real has ∼112,000 metric tonnes and average grade of 2700 ppm of U₃O₈, being one of the largest U deposits in the world and the largest in Brazil. Despite its economic and strategic importance, there are gaps in the geological knowledge of the Lagoa Real U deposits. One of them is the lack of extensive whole-rock chemical data sets. Here, we present whole-rock chemical analyses for major and trace elements, including the rare-earth elements (REE), from barren country rocks to uraniferous ore shoot, systematically sampled from an exploratory drill hole. The chemical data indicate that albitite rocks, with and without uraniferous mineralisation, cannot result from sodic syenitic magmatism, as proposed by recent studies. Petrographical and geochemical evidence supports the previously suggested concept that the Lagoa Real albitite rocks resulted from sodic metasomatism of the granitic country rock, known as the São Timóteo granite. Their ore-mineral assemblages and geochemical characteristics are similar to albitite-hosted U deposits worldwide.  相似文献   

Contrasting water–rock interaction behaviors of antimony and arsenic in contaminated rivers around an antimony mine,Hunan Province,China     

《Chemie der Erde / Geochemistry》2021,81(2):125748

Although antimony (Sb) and arsenic (As) exhibit similar geochemical behavior and toxicity in the environment, growing evidence suggests that their water–rock interaction behavior in contaminated rivers is quite different. Twenty-nine river water samples were collected between September and November 2018 from contaminated rivers around an antimony mine in Hunan Province, China. The concentrations of As and Sb were inversely proportional to the water flow distance. The rates and magnitudes of Sb decrease were more prominent than those of As. Silicate mineral dissolution from rocks such as silicified limestone increased the As and Sb concentration of in-mine-district (IMD) water. Dissolution of carbonate minerals, ion exchange, and competitive adsorption were the major water–rock interactions, resulting in rapidly decreasing As and Sb concentration in IMD direct impacted water and IMD indirect impacted water. The behaviors of As and Sb during water–rock interaction were dissimilar for areas dominated by carbonate and silicate minerals.  相似文献   

Composition and origin of the volatile components released from the Pesyanoe aubrite by stepwise crushing and heating     

《Chemie der Erde / Geochemistry》2021,81(1):125686

Aubrites are achondritic meteorites (enstatite pyroxenites) that were formed in highly reduced magmatic environments on a differentiated parent body sharing a common oxygen isotope reservoir with enstatite chondrites (EC), Earth and Moon, and could be considered as a geochemical model of the early proto-Earth. Some pyroxenes of the Pesyanoe aubrite have high abundance of gaseous inclusions, captured during the crystallization of the rocks. Investigation of the inclusions by IR spectroscopy reveals presence of OH⁻ groups and C–H bonds. The former are assigned to protonated point defects in enstatite lattice and the latter to compounds occupying void walls. Molecular water and CO₂ were not observed. Volatile components released from the samples of the Pesyanoe enstatite by stepwise crushing and heating are composed of CO₂, H₂O and a non-condensable phase. Hydrogen isotopic composition of volatiles extracted in form of molecular water in Px-separates varies in the range δD = −61 – −84‰ with mean value of δD = −73 ± 16‰ VSMOW and is within the ranges of ECs and Earth’s mantle. The total abundance of H₂ in the pyroxene of Pesyanoe were estimated as at least 0.047 ppm that is too low in comparison with that of enstatite chondrites (≥30 ppm H₂) and could indicate nearly complete degassing of the Pesyanoe primitive precursor material during the Pesyanoe parent body accretion or a mantle degassing in igneous differentiation process. In a last case a primitive precursor could have D/H ratio different from that of enstatite chondrites.  相似文献   

季冻区草炭土非线性K-G模型试验研究          下载免费PDF全文

高康  徐燕  胡天明  韩伶敏 《探矿工程》2021,48(1):112-119

季冻区草炭土是沼泽环境中植物残体在氧化分解作用下,堆积形成的含有大量未分解纤维残体的特殊土。草炭土纤维及其含量对其强度和变形特性具有重要影响,目前考虑纤维含量对草炭土强度和变形特性影响的本构关系研究还相对匮乏。K-G本构模型因其模型参数与土的体积模量和剪切模量能建立直接联系,因此在岩土工程非线性理论和数值计算分析方面广泛应用。以不同纤维含量的草炭土为研究对象,进行三轴剪切试验,研究了草炭土的应力应变曲线,得到了草炭土非线性K-G模型参数,分析了各模型参数随纤维含量的变化规律,建立了模型参数与纤维含量之间的线性函数关系。  相似文献   

基于水热耦合的青藏高原分布式水文模型——Ⅱ.考虑冰川和冻土的尼洋河流域水循环过程模拟          下载免费PDF全文

刘扬李  周祖昊  刘佳嘉  王鹏翔  李玉庆  朱熠明  姜欣彤  王康  王富强 《水科学进展》2021,32(2):201-210

尼洋河流域是雅鲁藏布江第四大支流,受冰川、积雪和冻土影响,水循环关系极其复杂。为深入研究该区域内的水文循环过程,本文在寒区水循环模型（WEP-COR）的基础上,针对青藏高原气候和地质特点,构建了耦合“积雪-土壤-砂砾石层”连续体和“积雪-冰川”水热过程模拟的青藏高原分布式水循环模型（WEP-QTP）。在尼洋河流域通过对2013—2016年的流量过程模拟发现,工布江达和泥曲站的逐月流量Nash-Sutcliffe效率系数分别达到0.810和0.752,比改进前的0.430和0.095有明显提升;以2015年为例,对比WEP-COR和WEP-QTP模型发现,WEP-QTP模型在汛期特别是主汛前（冻土融化期）模拟的流量过程不会出现较大的波动,模拟得到的逐日流量Nash-Sutcliffe效率系数相比WEP-COR从-0.67提高到0.54。模型增强了地下水含水层的调节作用,使得流量过程更加平稳且接近实测,研究结果表明,WEP-QTP模型适用于青藏高原的水文模拟。  相似文献   

寒区渠基黏土热参数最优概率分布     

石梁宏  李双洋 《吉林大学学报(地球科学版)》2021,51(2):473-482

为分析寒区渠基黏土热参数的随机分布特征及概率分布模型,以寒区渠基黏土的导热系数为样本,结合经典分布拟合法、多项式逼近法、最大熵法和正态信息扩散法,分别对寒区渠基黏土热参数的概率分布规律进行了研究。首先通过分析热参数的离散性,并比较概率分布曲线、拟合检验值和累计概率分布值,对不同方法描述热参数随机性的优劣进行了评价;然后,基于寒区渠基黏土热学参数对温度的敏感性,提出了一个可以达到理想拟合精度的寒区渠基黏土热参数概率推断的区间取值标准。研究结果表明：寒区渠基黏土的热参数具有随机变量的特征;正态信息扩散法可以描述热参数样本的随机波动性;在4种方法中,正态信息扩散法的拟合精度最高。使用3.5σ法,将[μ-3.5σ,μ+3.5σ]（μ为随机变量的均值,σ为标准差）作为概率函数推断时的取值区间,同时考虑偏度的影响,可使得累计概率值达到1.000 0的精度,能够较准确地推断热参数的概率分布函数。  相似文献   

基于孔压静力触探的岩土参数正态性检验方法对比     

林军  蔡国军  刘松玉  邹海峰  侯新宇 《吉林大学学报(地球科学版)》2021,51(5):1408-1415

岩土参数的正态分布是岩土工程可靠分析的基本假定之一。目前,岩土工程参数的正态性检验以KS （Kolmogorov-Smirnov）检验为主,然而诸多研究表明,对于小样本数据,KS检验的正态性检验结果并不可靠。本文以废黄河泛滥沉积相粉土中的孔压静力触探（CPTU）锥尖阻力q_t数据为研究对象,首先采用ANOVA （方差分析）检验,从CPTU测试资料中进行总体的样本筛选,然后应用SW （Shapiro-Wilk）检验、KS检验、LF （Lilliefors）检验和AD （Anderson-Darling）检验等4种正态性检验方法,在不同样本容量条件下,对测试数据进行正态性检验评价。当测试数据的样本容量充足时,分析结果表明：SW检验结果最为严格,KS检验结果最不保守,而LF检验和AD检验的严格性介于两者之间;对于常规岩土工程设计,采用KS检验结果即可满足稳定性分析要求,对于复杂岩土工程设计,采用SW检验对设计参数进行正态性检验,可降低设计的不确定性。  相似文献   

鲁西金岭矽卡岩型铁矿区早白垩世石英闪长岩成因:年代学和地球化学证据     

张超  崔芳华  耿瑞  张照录  高明波  高继雷 《矿物岩石》2021,41(1):80-92

金岭岩体是鲁西地区代表性的中生代侵入杂岩体,与金岭矽卡岩型铁矿的成因密切相关。为了解石英闪长岩的成因及与矽卡岩铁矿成矿关系,本次研究对金岭杂岩体中的石英闪长岩进行了年代学、地球化学及锆石Lu—Hf同位素和角闪石矿物微区成分的系统研究。LA-ICP-MS锆石U-Pb年代学显示石英闪长岩加权平均年龄为(128±1) Ma,侵位时代为早白垩世;样品具有较低的w(SiO_2)(58.34%~65.22%),和高的w(Al_2O_3)(14.95%~15.72%),w(Na_2O)为4.44%~5.16%,w(K_2O)为2.26%~5.17%,w(CaO)为3.39%~6.30%,w(Fe_2O_3~T),w(MgO)含量变化范围较大,分别为2.21%~6.86%和2.32%~5.21%,此外,样品具有较高的Sr含量(682~834×10^-6)、Ba含量(1 130~1 595×10^-6),表现出高Ba, Sr花岗岩的岩石地球化学特征。石英闪长岩中角闪石为岩浆成因角闪石,具有壳源岩浆成因角闪石的特征,其结晶时的氧逸度为△NNO+0.83~△NNO+1.87,温压条件为849~1 092℃和89~279 MPa。石英闪长岩含有较高的Ni含量、Co含量、Cr含量以及Mg~#,其Nb/Ta, Zr/Hf, Rb/Sr和Ba/Rb比值接近原始地幔平均值。样品含有~2.5Ga的捕获锆石,所有锆石的ε_Hf(t)值为负值。锆石Hf同位素和岩石地球化学特征表明石英闪长岩侵位深度为3.9~10.3 km,岩浆源区为岩石圈地幔并受到地壳物质的混染。  相似文献   

断陷湖盆缓坡带古河道定量恢复方法及油气地质意义：以霸县凹陷文安斜坡东营组为例     

张自力  朱筱敏  陈贺贺  张锐锋  曹兰柱  施瑞生  谢爽慧 《高校地质学报》2021,27(5):501-514

河流沉积砂体定量表征是油田高效勘探开发的重要基础。文章综合利用定量岩心分析、测井相分析、定量地震沉积学和三维地震剖面识别方法,对霸县凹陷文安斜坡东营组古河道砂体厚度,河道（带）宽度,（满岸）河道水深等河流参数进行了定量化计算。研究表明,文安斜坡东营组发育北部苏桥、中部文安和南部长丰镇三个物源输入口,河流呈NEE-SWW向分散于文安斜坡带,其中河道带宽度（w）为1.04~2.61 km,平均宽度（wcb）为1.71 km;主河道宽度（W）为15.2~179.6 m,平均宽度（Wc）为84.4 m;主河道沉积水深（D）为1.34~5.21 m,平均水深（Dc）为3.29 m;主河道满岸水深（Dmax）为2.35~9.15 m,平均满岸水深（Dmaxa）为5.77 m;主河道沉积厚度（H）为2.15~8.32 m,平均厚度（Hc）为5.25 m,河道长度（L）为18.5~28.2 km,平均河道带长度（Lcb）为25.1 km,流向（A）为40°~65°。确定文安斜坡东营组发育辫状河沉积,斜坡东侧中外带为主要的砂岩卸载区,河流以垂向挖掘性河流为主,侧向迁移为辅,河道砂岩平面呈“条—带”状。文安斜坡西侧内带以侧向迁移河流为主,下蚀作用为辅,河道砂岩呈“席—带”状。东营组河道砂岩具有“下生上储”的有利成藏条件,具有良好的岩性、构造—岩性圈闭（油气藏）勘探前景。  相似文献   

The relationship between groundwater and natural vegetation in Qaidam Basin          下载免费PDF全文

Dang Xue-ya  Lu Na  Gu Xiao-fan  Jin Xiao-mei 《地下水科学与工程》2021,9(4):341-349

To accurately evaluate ecological risks trigged by groundwater exploitation, it must be clarified the relationship between vegetation and groundwater. Based on remote sensing data sets MOD13Q1, groundwater table depth (WTD) and total dissolved solids (TDS), the relationship between groundwater and natural vegetation was analyzed statistically in the main plain areas of Qaidam Basin. The results indicate that natural vegetation is groundwater-dependent in areas where WTD is less than 5.5 m and TDS is less than 7.5 g/L. Aquatic vegetation, hygrophytic vegetation and hygrophytic saline-alkali tolerant vegetation are mainly distributed in areas with WTD <1.1 m. Salt-tolerant and mesophytic vegetation mainly occur in areas with WTD of 1.4-3.5 m, while the xerophytic vegetation isprimarily present in areas where WTD ranges from 1.4 m to 5.5 m. Natural vegetation does not necessarily depend on groundwater in areas with WTD >5.5 m. For natural vegetation, the most suitable water TDS is less than 1.5 g/L, the moderately suitable TDS is 1.5-5.0 g/L, the basically suitable TDS is 5.0-7.5 g/L, and the unsuitable TDS is more than 7.5 g/L.  相似文献